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A facile synthesis of cyclononatripyrroles.
Autorzy
Rok wydania
2007
Czasopismo
Numer woluminu
9
Strony
4785-4787
DOI
10.1021/ol702119y
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A facile synthesis of a functionalized cyclononatripyrrole derivative is described. It involves the iodine-catalyzed cyclotrimerization of ethyl 3,3-dimethyl-5,7-dihydro[1,3]dioxepino[5,6-c]pyrrole-6-carboxylate in methanol. The product obtained in this way exists solely in the crown conformation typical of cyclononatripyrroles. However, in contrast to previously reported compounds of this class, it possesses three labile methoxymethyl arms that can be further functionalized under acidic conditions.
Adres publiczny
https://doi.org/10.1021/ol702119y
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