Repozytorium
Wyszukaj
Kolekcje
Inne
Facile synthesis and crystal structure of 1,5-dimethyl-6-thioxo-1,3,5-triazinane-2,4-dione.
Autorzy
Rok wydania
2015
Czasopismo
Journal of Structural Chemistry
Numer woluminu
56
Strony
806-810
DOI
10.1134/S0022476615040332
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The title compound 1,5-dimethyl-6-thioxo-1,3,5-triazinane-2,4-dione C5H7N3O2S is synthesized via the reaction between N,N′-dimethylthiourea and trichloroacetyl isocyanate in dichloromethane. The structure of the title compound is characterized by IR, 1HNMR, 13C NMR, elemental analysis, and single-crystal X-ray diffraction. The crystal structure reveals the role of N–H...O and C–H...O hydrogen bonds, and C=O...π interactions in the arrangement of the molecules into ribbons, which are further joined to each other to form double-layers parallel to the (001) plane.
Słowa kluczowe
N, N′-dimethylthiourea, trichloroacetyl isocyanate, triazinane, X-ray diffraction
Adres publiczny
Podobne publikacje
Structure, electrochemistry and hydroformylation catalytic activity of the bis(pyrazolylborato)rhodium(I) complexes [RhBp(CO)P] [P=P(NC4H4)3, PPh3, PCy3, P(C6H4OMe-4)3].
Trzeciak Anna M., Borak Beata, Ciunik Zbigniew, Ziółkowski Józef J., Guedes da Silva M. Fátima. C., Pombeiro Armando J. L.
Complexes of Yb3+ with EDTA and CDTA - molecular and electronic structure.
Janicki Rafał, Starynowicz Przemysław, Mondry Anna
Dinuclear complexes of copper(I) with crown ether-containing N-Thiophosphorylated bis-thioureas and 2,2'-bipyridine or 1,10-phenanthroline: synthesis, characterization, and picrate extraction properties.
Babashkina Maria G., Shakirova E. R., Safin Damir A., Sokolov F. D., Klein A., Szyrwiel Łukasz, Kubiak Maria, Kozłowski Henryk, Krivolapov D. B.