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Inne
Facile one-pot synthesis of hybrid compounds based on decavanadate showing water oxidation activity.
Autorzy
Rok wydania
2020
Czasopismo
Inorganic Chemistry Communications
Numer woluminu
119
Strony
108111/1-108111/6
DOI
10.1016/j.inoche.2020.108111
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Herein, we report the synthesis of two hybrid compounds based on decavanadate anion, namely, [Cu(dien)
(Hdien)]2[V10O28]·2H2O (1) and (H3dien)2[V10O28]·4H2O (2), where dien=diethylenetriamine, obtained under mild conditions. Both compounds were characterized by elemental, TG/DTA, single crystal and powder X-ray diffraction analyses, IR and EPR spectroscopies. The compound 1 was found to be active as homogeneous photochemical oxidation catalyst of water to dioxygen.
Słowa kluczowe
Decavanadate, Copper, EPR spectroscopy, Catalysis, Water splitting
Adres publiczny
http://dx.doi.org/10.1016/j.inoche.2020.108111
Strona internetowa wydawcy
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