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The formation of molecular compounds in the reaction between [MgCl2(THF)2] and [MoCl3O(THF)2]. Crystal structure of [{MoCl4O(THF)}2Mg(THF)4]·CH2Cl2.

Autorzy

Piotr Sobota

Jolanta Ejfler

Tadeusz Płuziński

Tadeusz Lis

Rok wydania

1991

Czasopismo

Polyhedron

Numer woluminu

10

Strony

2457-2461

DOI

10.1016/S0277-5387(00)86207-5

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The interaction of [MgCl2(THF)2] with [MoCl3O(THF)2] in 1:1 and 1:2 ratios in CH2Cl2 gave the paramagnetic complexes [(THF)3Mg(μ-Cl)3MoCl2O] I and [{MOCl4O(THF)}2Mg(THF)4]·CH2Cl2 II (THF, tetrahydrofuran). In complex I, the molybdenum and magnesium atoms are octahedrally surrounded by three bridging chlorine atoms and terminal oxo-oxygen and two chlorine atoms and by three THF molecules, respectively. Complex II consists of Mg2+ ions coordinated by four THF molecules and two trans[MoCl4O(THF)]− anions coordinated to an Mg atom by oxo O-atoms.

Adres publiczny

https://doi.org/10.1016/S0277-5387(00)86207-5

Strona internetowa wydawcy

http://www.elsevier.com

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1998

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1996

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