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Polynuclear aggregation of manganese dichloride. Syntheses, properties and structures of polymeric [MnCl2(THF)1,6]∞, dimeric [(THF)4Mg(μ-Cl2Mn Cl2], and ionic [Mg(H2O)2(THF)4][Mg(H2O)4(THF)2][MnCl4]2·2THF compounds.
Autorzy
Rok wydania
1998
Czasopismo
Numer woluminu
37
Strony
3428-3431
DOI
10.1021/ic971513i
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The crystallization of MnCl2 in tetrahydrofuran results in the formation of polymeric [MnCl2(THF)1.6] (1) with an unexpected structure. This species represents the first crystallographically defined example of tetranuclear [Mn4(μ3-Cl)2(μ2-Cl)4Cl2(THF)6] units linked by MnCl2(THF)2 moieties. Our observations highlight the importance of the M4X6 core present in 1 as a component of α-olefin polymerization catalysts.
Słowa kluczowe
Iron, Chemical structure, Tetrahydrofurans, Transition metals, Cobalt
Adres publiczny
https://doi.org/10.1021/ic971513i
Strona internetowa wydawcy
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