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The crystal structures and properties of [VCl3(THF)2(H2O)] and VCl3(THF)2(H2O)]· THF.

Autorzy

Piotr Sobota

Igor O. Fritsky

Jolanta Ejfler

Sławomir Szafert

Tadeusz Głowiak

Rok wydania

1996

Czasopismo

Polyhedron

Numer woluminu

15

Strony

381-384

DOI

10.1016/0277-5387(95)00286-2

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The structure of the products formed between [mer-VCl3(THF)3] and water in tetrahydrofuran (THF) or dichloromethane were investigated. Two different crystalline species were isolated: [VCl3(THF)2(H2O)] (1) and [VCl3(THF)2(H2O)]·THF (2). Their structures were determined by means of X-ray analysis. In both compounds the vanadium (III) ions are in a distorted octahedral environment surrounded by three mer-chlorine atoms, two trans-situated THF molecules and a water molecule.

Adres publiczny

https://doi.org/10.1016/0277-5387(95)00286-2

Strona internetowa wydawcy

http://www.elsevier.com

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