Repozytorium

Infrared bandshapes of intramolecularly H-bonded systems-III. Vibrational dephasing of νs(OH) in 2,6-dichlorophenol.

Autorzy

Małgorzata Broda

Jerzy P. Hawranek

Rok wydania

1987

Czasopismo

Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy

Numer woluminu

43

Strony

617-619

DOI

10.1016/0584-8539(87)80142-3

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The shape of the vs (OH) absorption band of intramolecularly H-bonded 2,6-dichlorophenol was measured in a series of solvents of increasing polarity and quantitatively analyzed. A distinct dependence of band positions, shape parameters, band moments, integrated intensities, correlation functions and correlation times on the polarity of solvent has been found. Vibrational dephasing due to dipole—dipole interactions seems to be an important relaxation pathway determining the bandshape in the studied systems.

Adres publiczny

https://doi.org/10.1016/0584-8539(87)80142-3

Strona internetowa wydawcy

http://www.elsevier.com

Podobne publikacje
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Vibrational dephasing of υs(OH) in 2,4-dichlorophenol.

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