Repozytorium
Wyszukaj
Kolekcje
Inne
Vibrational dephasing of υs(OH) in 2,4-dichlorophenol.
Autorzy
Rok wydania
1990
Czasopismo
Journal of Molecular Structure
Numer woluminu
219
Strony
215-220
DOI
10.1016/0022-2860(90)80058-R
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A quantitative analysis of the infrared bandshape of νs(OH) in intramolecularly hydrogen-bonded 2,4-dichlorophenol in a series of solvents is presented. A distinct dependence of bandshape indices and relaxation parameters on the polarity of solvent has been found. The band shifts to lower wavenumbers, broadens and becomes more intense with increasing solvent polarity; correspondingly, the correlation function decays faster and the correlation time diminishes. The results are compared with those for previously studied systems. Factors influencing the bandshape are discussed.
Adres publiczny
https://doi.org/10.1016/0022-2860(90)80058-R
Strona internetowa wydawcy
Podobne publikacje
Infrared bandshapes of intramolecularly H-bonded systems-III. Vibrational dephasing of νs(OH) in 2,6-dichlorophenol
Broda Małgorzata, Hawranek Jerzy P.
Vibrational dephasing of νs(OH) in 2,6-dichloro-4-nitrophenol.
Broda Małgorzata, Hawranek Jerzy P.
Solvent dependence of the νs(OD) bandshape in 2,6-dichlorophenol.
Broda Małgorzata, Hawranek Jerzy P.