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Inne
Solvent dependence of the νs(OD) bandshape in 2,6-dichlorophenol.
Autorzy
Rok wydania
1994
Czasopismo
Journal of Molecular Structure
Numer woluminu
321
Strony
137-141
DOI
10.1016/0022-2860(93)08214-O
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The infrared bandshape of νs(OD) of 2,6-dichlorophenol is measured in a series of solvents of increasing polarity, and is quantitatively analysed. The bandshape is described in terms of band indices, moments, correlation functions and correlation times. A distinct solvent dependence of bandshape and relaxation parameters has been found. The changes of the νs(OD) bandshape with increasing solvent polarity are compared in detail with those obtained earlier for analogous solvents for νs(OH) of 2,6-dichlorophenol. The overall behaviour of the spectral and relaxation parameters is similar, but the changes are less distinct for the weaker OD ⋯ Cl bond.
Adres publiczny
https://doi.org/10.1016/0022-2860(93)08214-O
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