Repozytorium
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Kolekcje
Inne
Rhenium(I)–copper(I) carbonyl cyanide clusters.
Autorzy
Rok wydania
2020
Czasopismo
Journal of Organometallic Chemistry
Numer woluminu
908
Strony
121065/1-121065/7
DOI
10.1016/j.jorganchem.2019.121065
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Tetranuclear cyanide rhenium(I)–copper(I) coordination compounds were synthesized in the course of simple one-pot reactions in mild conditions. A new class of mixed-metal compounds based on rhenium(I) clusters that are comprised of the pseudo-rhombic-shaped {Re2Cu2(μ-CN)4} unit were found. Two kinds of geometries adopted by the self-assembled cyclic clusters are observed, both of which can be described as approximately block-like overall geometries with different coordination modes. The unique polynuclear structure {ReCu(CH3CN)(μ-CN)2(CO)2(PPh3)2}n can be formed under the reaction conditions. Presented compounds were characterised by single crystal X-ray diffraction and spectroscopic studies.
Słowa kluczowe
Re-Cu clusters, Tetranuclear metallacycles, Cyanide macrocyclic cluster, Rhenium carbonyl compounds
Adres publiczny
http://dx.doi.org/10.1016/j.jorganchem.2019.121065
Strona internetowa wydawcy
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