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[ReOCl3(PPh3)2] as a substrate for the synthesis of the rhenium(I) carbonyl complexes [Re(CO)2(OAc)(PPh3)2] and [ReCl(CO)3(PPh3)2].
Autorzy
Rok wydania
2013
Czasopismo
Journal of Organometallic Chemistry
Numer woluminu
733
Strony
60-62
DOI
10.1016/j.jorganchem.2013.03.001
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
New p reparative methods have been developed for the synthesis of the rhenium(I) carbonyl complexes[Re(CO)2(OAc)(PPh3)2](1) and [ReCl(CO)3(PPh3)2](2). Acetic anhydride was decarbonylated du ring thecourse of its reaction with [ReOCl3(PPh3)2], resulting in the formation of the rhenium(I) carbonylcomplex [Re(CO)2(OAc)(PPh3)2](1), which was subsequently conve rted almost quantitatively to[ReCl(CO)3(PPh3)2](2) via the decarbonylation of its aceta te group under acidic conditions.
Słowa kluczowe
Rhenium carbonyl complex, acetic anhydride, decarbonylation
Adres publiczny
http://dx.doi.org/10.1016/j.jorganchem.2013.03.001
Strona internetowa wydawcy
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