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Inne
Copper(II) chromate and dichromate complexes with polypyridines. Physicochemical and reactivity studies.
Autorzy
Rok wydania
1991
Czasopismo
Numer woluminu
10
Strony
2179-2184
DOI
10.1016/S0277-5387(00)86138-0
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Copper chromate and dichromate complexes with 2,2′-bipyridyl and 1,10-phenanthroline were synthesized and characterized (UV-vis, IR, FIR, ESR and thermal data). The coordination of the anion in the chromate complexes was proposed from the IR data. The ESR data for the powdered samples reflect both d x2-y2 anddz2 ground states for the copper ion whereas the glassy solution spectra exhibit only the former. The presence of the chromium(V) ion in the spectra of the complexes dissolved in the water-ethylene glycol mixture is discussed.
Adres publiczny
https://doi.org/10.1016/S0277-5387(00)86138-0
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