Repozytorium

Spectroscopic studies of PrBr3· 7H2O monocrystal.

Autorzy

Grażyna Oczko

Janina Legendziewicz

Jerzy Hanuza

Jacek Gliński

Lucyna Macalik

Rok wydania

1996

Czasopismo

Acta Physica Polonica A

Numer woluminu

90

Strony

431-438

DOI

10.12693/APhysPolA.90.431

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Single crystals of praseodymium tribromide heptahydrate were grown from aqueous solution. The IR, Raman, and high resolution absorption spectra were measured at room and low temperatures. The assignments of IR and Raman frequencies are reported. The temperature dependence of intensities was found and vibronic coupling in f-f transitions was analysed. Anisotropy of the intensities of optical lines was detected and taken into account in the Judd-Ofelt analysis of the f-f transitions probabilities. The results are compared to the available IR and electron spectroscopic data for other single crystals of lanthanide bromides.

Adres publiczny

https://doi.org/10.12693/APhysPolA.90.431

Strona internetowa wydawcy

http://www.ifpan.edu.pl

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