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Core modified porphyrins-a macrocyclic platform for organometallic chemistry.
Autorzy
Rok wydania
2005
Czasopismo
Coordination Chemistry Reviews
Numer woluminu
249
Strony
2510-2533
DOI
10.1016/j.ccr.2005.05.015
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
An alteration of a metalloporphyrin coordination core, exemplified by 21-heteroporphyrins and 2-aza-21-carbaporphyrin (N-confused porphyrin, inverted porphyrin), provides a route of choice to stabilize unusual oxidation states and coordination geometries, affording a stabilization of such rare species as organometallic high-spin nickel(II) or copper(II) derivatives. This review focuses on reactivity and electronic structure of peculiar organometallic compounds trapped due to the appropriate choice of the suitable macrocyclic platform.
Słowa kluczowe
Porphyrin, Porphyrinoids, Heteroporphyrins, Organometallic chemistry
Adres publiczny
https://doi.org/10.1016/j.ccr.2005.05.015
Strona internetowa wydawcy
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