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Inne
1 D coordination polymer with octahedral and square-planar nickel(II) centers.
Autorzy
Rok wydania
2013
Czasopismo
Inorganic Chemistry Communications
Numer woluminu
29
Strony
82-84
DOI
10.1016/j.inoche.2012.12.008
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Synthesis of an interesting Ni(II) 1D-chain, [Ni3(ashz)2(DMF)2(H2O)2]n·4DMF (1·4DMF), derived from N-acetylsalicylhydrazide (H3ashz) has been reported. The unprecedented bridging coordination mode involving the phenoate oxygen of ashz3 − leads to the formation of a polynuclear 1D-chain without any additional spacer ligand. The coordination polymer 1 contains the Ni(II) cations in octahedral and in square-planar environments and shows antiferromagnetic interactions.
Słowa kluczowe
Nickel coordination polymer, N-acetylsalicylhydrazide 1D chain, Antiferromagnetic interaction, X-ray crystallography
Adres publiczny
http://dx.doi.org/10.1016/j.inoche.2012.12.008
Strona internetowa wydawcy
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