Repozytorium

Synthesis, spectroscopic investigations, X-ray studies and magnetic properties of novel three-dimensional thiocyanato-bridged manganese(II)-mercury(II) coordination polymers.

Autorzy

Barbara Machura

J. Palion

Jerzy Mroziński

Bożena Kalińska

Rafał Kruszyński

Rok wydania

2013

Czasopismo

Polyhedron

Numer woluminu

49

Strony

216-222

DOI

10.1016/j.poly.2012.10.004

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Three novel heterobimetallic coordination polymers [Mn(Me-Im)2Hg(SCN)4]n (1, Me-Im = N-methyl-imidazole), [Mn(tp)(MeOH)Hg(SCN)4]n (2, tp = 1,2,4-triazolo-[1,5-a]pyrimidine) and [Mn(bopy)2Hg(SCN)4]n (3, bopy = 2-benzoylpyridine) have been synthesized and characterized by spectroscopic methods, single crystal X-ray diffraction analysis and magnetic measurements. X-ray analysis reveals that the compounds create three-dimensional coordination polymers. Variable-temperature magnetic susceptibility measurements show very weak antiferromagnetic interactions between the paramagnetic Mn(II) centers of structures 1, 2 and 3.

Słowa kluczowe

Coordination polymer, manganese, mercury, Thiocyanate bridge, X-ray, Magnetic measurements

Adres publiczny

http://dx.doi.org/10.1016/j.poly.2012.10.004

Strona internetowa wydawcy

http://www.elsevier.com

Podobne publikacje
2010

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