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Inne
Comparison of 1-hydroxymethyl-3,5-dimethylpyrazole and 1-benzyl-2-hydroxymethylimidazole coordination properties towards copper(II).
Autorzy
Rok wydania
2002
Czasopismo
Inorganic Chemistry Communications
Numer woluminu
5
Strony
1056-1058
DOI
10.1016/S1387-7003(02)00645-7
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Using 1-hydroxymethyl-3,5-dimethylpyrazole as the starting ligand and 2-propanol as the solvent and a molar ratio Cu:L, 1:4, a dinuclear Cu(II) complex has been obtained. The microanalytical data and the crystal structure reveal that the dicopper complex with two bridging methoxide groups contains the 3,5DMePz, 1-CH2O-3,5DMePz and BF4− ligands which are received during the coordination process. The compound shows an antiferromagnetic intramolecular interaction between the Cu(II) ions.
Słowa kluczowe
Crystal structures, Dicopper(II) complex, Pyrazole complex, Alkoxo bridged compounds
Adres publiczny
https://doi.org/10.1016/S1387-7003(02)00645-7
Strona internetowa wydawcy
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