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Inne
Anion assisted self-assembly of a Ni(II) complex into metallo-supramolecular network involving H-bonded synthons as nodes.
Autorzy
Rok wydania
2010
Czasopismo
Journal of Molecular Structure
Numer woluminu
964
Strony
18-26
DOI
10.1016/j.molstruc.2009.11.005
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A trinuclear nickel complex {[Ni3(HAmTrz)6·6H2O]·2H2O·6NO3]}n 1 has been synthesized under hydrothermal condition and characterized by single-crystal X-ray crystallography, elemental analysis, IR, and TG/DTA. Nitrate anions of the crystal lattice are found to play an important role in the molecular self-assembly of [Ni3(HAmTrz)6.6H2O]6+ cationic building block into an overall three-dimensional network of 1 involving variety of homomeric and heteromeric , , supramolecular synthons. Furthermore, the material exhibits magnetic interaction of the Ni(II) centers existing in the whole trimeric building block.
Słowa kluczowe
Trinuclear nickel triazolate complex, H-bonding synthons, Molecular self-organization, Magnetic interactions
Adres publiczny
https://doi.org/10.1016/j.molstruc.2009.11.005
Strona internetowa wydawcy
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