Repozytorium
Wyszukaj
Kolekcje
Inne
Structure and magnetic properties of a trinuclear nickel(II) complex with benzenetricarboxylate bridge.
Autorzy
Rok wydania
2008
Czasopismo
Numer woluminu
361
Strony
3723-3729
DOI
10.1016/j.ica.2008.04.005
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Novel trinuclear Ni(II) complex [Ni3(pmdien)3(btc)(H2O)3](ClO4)3 · 4H2O, 1 where pmdien = N,N,N′,N′,N″-pentamethyldiethylenetriamine, H3btc = 1,3,5-benzenetricarboxylic (trimesic) acid, has been prepared and structurally characterized. Three nickel atoms are bridged by btc trianion and their coordination sphere is completed by three N atoms of pmdien and O atom of the water molecule. The three nickel(II) magnetic centers are equivalent and their coordination spheres are completed to deformed octahedrons. Magnetic susceptibility was measured over the temperature range 1.8–300 K and zJ′ = −0.19 cm−1, D = 3.79 cm−1, g = 2.18 parameters were calculated.
Słowa kluczowe
Nickel complex, Benzenetricarboxylate, Trinuclear complexes, Trimesic acid, Crystal structure, Magnetism
Adres publiczny
https://doi.org/10.1016/j.ica.2008.04.005
Strona internetowa wydawcy
Podobne publikacje
Products of reactions between ReX3 (X = Cl, I) and N-heterocyclic compounds - structural and spectroscopic studies.
Krawczyk Monika K., Krawczyk Marta S., Siczek Miłosz, Lis Tadeusz
Crystal structure of μ3-oxo-esakis(μ2-acetate)triaquatrichromium(III) 2,6-dihydroxybenzoate dihydrate.
Głowiak Tadeusz, Kozłowski Henryk, Strinna-Erre L., Micera Giovanni
Reaction of [(Co)4Mo(μ-Cl)3Mo(SnCl3)(CO)3] with PhC≡CPh. X-ray crystal structure of [Mo3(μ3-Cl)(μ2-Cl)(μ2-OH)2(O)(η2-PhC≡CPh)5].
Szymańska-Buzar Teresa, Głowiak Tadeusz, Czeluśniak Izabela