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Kolekcje
Inne
Cu(II), Cd(II) and Ni(II) azide complexes incorporating bis(3,5-dimethylpyrazol-1-yl)methane-synthesis, spectroscopic characterisation, X-ray studies and magnetic properties.
Autorzy
Rok wydania
2011
Czasopismo
Numer woluminu
30
Strony
2815-2823
DOI
10.1016/j.poly.2011.08.007
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Three novel compounds [Cu2(μ1,1-N3)2(N3)2(bdmpzm)2] (1) [Cd(N3)2(bdmpzm)]n (2) and [Ni(N3)2(bdmpzm)2] (3) have been synthesised and characterised structurally and spectroscopically. The structure 1 consists of a neutral dinuclear [Cu2(μ1,1-N3)2(N3)2(bdmpzm)2] entities, compound 2 has one-dimensional zigzag chain structure extending along the crystallographic direction [1 0 0] with alternating di-μ1,1-N3 and di-μ1,3-N3 bridges, and 3 is a mononuclear complex. The experimental studies on the nickel(II) complex have been accompanied computationally by the density functional theory (DFT) calculations.
Słowa kluczowe
Coordination Chemistry, copper, Cadmium, nickel, azide ligand, Bis(3, 5-dimethylpyrazol-1-yl)methane, X-ray, magnetic measurements
Adres publiczny
https://doi.org/10.1016/j.poly.2011.08.007
Strona internetowa wydawcy
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