Repozytorium

Synthesis, magnetic behavior and structural characterization of novel one-dimensional copper(II) coordination polymer based on azide and oxalate bridges.

Autorzy

Anna Świtlicka-Olszewska

Barbara Machura

Jerzy Mroziński

Rok wydania

2014

Czasopismo

Inorganic Chemistry Communications

Numer woluminu

43

Strony

86-89

DOI

10.1016/j.inoche.2014.02.013

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

A novel compound [Cu21,1–N3)2(C2O4)(bpzm)2]n incorporating simultaneously azide and oxalate bridges has been synthesized and characterized in the context of its structural and magnetic properties. The crystal structure has been determined by single-crystal X-ray analysis. Additionally, the compound was characterized using IR, UV–vis and thermal analyses. The investigated complex [Cu21,1–N3)2(C2O4)(bpzm)2]n represents an interesting magnetic system of Cu(II) centers with alternating ferro- and antiferromagnetic coupling.

Słowa kluczowe

coordinaton polymer, copper(II), oxalate, azide, X-ray, magnetic measurements

Adres publiczny

http://dx.doi.org/10.1016/j.inoche.2014.02.013

Strona internetowa wydawcy

http://www.elsevier.com

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