Repozytorium

Matrix effects on hydrogen-bonded complexes trapped in low-temperature matrices.

Autorzy

Austin J. Barnes

Zofia Mielke

Rok wydania

2012

Czasopismo

Journal of Molecular Structure

Numer woluminu

1023

Strony

216-221

DOI

10.1016/j.molstruc.2012.05.020

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

There are several different possible matrix effects on hydrogen-bonded complexes trapped in low-temperature matrices: hydrogen-bonded complexes may be stabilised (compared with the gas phase) as a result of being trapped in a low-temperature matrix; metastable hydrogen-bonded complexes may be trapped in matrices; the matrix may influence the extent of proton transfer in a hydrogen-bonded complex; the matrix may influence the structure of a hydrogen-bonded complex. Each of these possible effects is examined in turn using selected examples from the literature as well as our own work.

Słowa kluczowe

hydrogen-bonded complexes, matrix effects, Matrix isolation

Adres publiczny

http://dx.doi.org/10.1016/j.molstruc.2012.05.020

Strona internetowa wydawcy

http://www.elsevier.com

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