Repozytorium
Wyszukaj
Kolekcje
Inne
The interaction of formohydroxamic acid with nitrogen: FTIR matrix isolation and ab initio studies.
Autorzy
Rok wydania
2004
Czasopismo
Journal of Molecular Structure
Numer woluminu
708
Strony
183-188
DOI
10.1016/j.molstruc.2004.05.020
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Argon matrix infrared spectra of the complexes formed between formohydroxamic acid, HCONHOH (FHA) and nitrogen have been recorded. The experimental results indicate formation of two isomeric complexes in which the nitrogen atom of the N2 molecule is attached to the NH or OH groups of FHA. Theoretical studies of the structure and spectral characteristics of the complexes were carried out on the MP2 level with the 6-311++G(2d,2p) basis set. The calculated vibrational frequencies for the complexes present in the matrices are in good agreement with the experimental data.
Słowa kluczowe
Formohydroxamic acid, Nitrogen, Hydrogen bond, Molecular complexes, Matrix isolation, Infrared spectra
Adres publiczny
https://doi.org/10.1016/j.molstruc.2004.05.020
Strona internetowa wydawcy
Podobne publikacje
Infrared matrix isolation studies of the acetohydroxamic acid complexes with HF and HCl.
Sałdyka Magdalena, Mielke Zofia
Structure and photochemistry of nitrous acid-methanethiol complexes in solid argon.
Grzechnik Katarzyna, Mielke Zofia