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Kolekcje
Inne
Dinuclear Rh(II) complexes with one polypyridyl ligand, structure, properties and antitumor activity.
Autorzy
Rok wydania
2010
Czasopismo
Numer woluminu
363
Strony
2401-2408
DOI
10.1016/j.ica.2010.03.061
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Rhodium(II) complexes [Rh2(μ-OAc)2(OAc)(bpy)(H2O)2]PF6 (1), [Rh2(μ-OAc)2(OAc)(phen)(H2O)2](PF6)·H2O (2), [Rh2(μ-OOCCH3)3(OOCCH3)(phen)] (3) and [Rh2(μ-O2CCH3)3(O2CCH3)(Ph2phen)] (4) (Ph2phen = 4,7-diphenyl-1,10-phenanthroline) have been synthesized and characterized by means of NMR, IR and UV–Vis spectroscopic methods. X-ray structure of complex 4·1.5(CH3COCH3) has been determined and its geometry and electronic structure has been elucidated using OPBE and B3LYP DFT methods. The compounds are active cytostatic agents against tumor cells.
Słowa kluczowe
Rhodium(II), Dinuclear rhodium complexes, Polypyridyls, Antitumor activity, DFT calculation, UV–Vis spectra
Adres publiczny
https://doi.org/10.1016/j.ica.2010.03.061
Strona internetowa wydawcy
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