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Inne
Aromatic and antiaromatic pathways in triphyrin(2.1.1) annelated with benzo[b]heterocycles.
Autorzy
Rok wydania
2019
Czasopismo
Numer woluminu
25
Strony
15477-15482
DOI
10.1002/chem.201903863
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Understanding of the aromatic properties and magnetically induced current densities of highly conjugated chromophores is important when designing molecules with strongly delocalized electronic structure. Linear extension of the triphyrin(2.1.1) skeleton with an annelated benzo[b]heterocycle fragment modifies the aromatic character by extending the electron delocalization pathway. Two‐electron reduction leads to an antiaromatic triphyrin(2.1.1) ring and an aromatic benzo[b]heterocycle subunit. Current‐density calculations provide detailed information about the observed pathways and their strengths.
Słowa kluczowe
acenes, antiaromaticity, aromaticity, chirality, triphyrin
Adres publiczny
http://dx.doi.org/10.1002/chem.201903863
Strona internetowa wydawcy
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