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Kolekcje
Inne
New mononuclear manganese(II) and zinc(II) complexes with a terpyridine ligand: structural, magnetic and spectroscopic properties.
Autorzy
Rok wydania
2011
Czasopismo
Numer woluminu
30
Strony
730-737
DOI
10.1016/j.poly.2010.12.032
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Six mononuclear complexes of the dimethylterpyridine ligand 1,3-bis(6-methylpyridin-2-yl)pyridine, L, C17H15N3, of the general formula MLX2 were prepared from different manganese(II) and zinc(II) salts (M = Mn(II), X = Cl− – 1a, Br− – 1b, – 1c and – 1d; M = Zn(II), X = Cl− – 2a and – 2c). The complexes have been characterized through analytical, spectroscopic (UV–Vis, ESI-MS, and IR) and magnetic measurements. Single crystal X-ray structure analyses of these complexes revealed five-coordinate metal ions in 1a, 1c, 2a and 2c, whereas 1d turned out to contain a six-coordinate Mn(II) ion.
Słowa kluczowe
Coordination modes, manganese, zinc, magnetic properties
Adres publiczny
https://doi.org/10.1016/j.poly.2010.12.032
Strona internetowa wydawcy
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