Repozytorium

Infrared matrix isolation studies of the acetohydroxamic acid complexes with HF and HCl.

Autorzy

Magdalena Sałdyka

Zofia Mielke

Rok wydania

2004

Czasopismo

Journal of Molecular Structure

Numer woluminu

692

Strony

163-168

DOI

10.1016/j.molstruc.2004.01.026

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Argon matrix infrared spectra of the complexes formed between acetohydroxamic acid (CH3CONHOH) and hydrogen halides (HF, HCl) have been recorded. The experimental results indicate formation of a strong binary complex in which the hydrogen halide molecule acts as a proton donor towards the carbonyl group of acetohydroxamic acid. The H–X stretches and several perturbed CH3CONHOH vibrations were identified for the two HX complexes; for the HF complex the two librational HF modes were also observed.

Słowa kluczowe

Acetohydroxamic acid, Hydrogen halides, Hydrogen bond, Infrared spectra, Matrix isolation

Adres publiczny

https://doi.org/10.1016/j.molstruc.2004.01.026

Strona internetowa wydawcy

http://www.elsevier.com

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