Repozytorium

β-alanine-hydrochloride (2:1) crystal: structure,13 C NMR and vibrational properties, protonation character.

Autorzy

Dorota Godzisz

Marek Ilczyszyn

Zbigniew Ciunik

Rok wydania

2003

Czasopismo

Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy

Numer woluminu

59

Strony

235-244

DOI

10.1016/S1386-1425(02)00116-6

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The crystal structure of β-alanine–hydrochloride (2:1) complex (2A-HCl) has been determined by X-ray diffraction method at 298 and 100 K as monoclinic, space group C2/c, Z=4. The crystal comprises chloride anions and protonated β-alanine dimers: two β-alanine zwitterions are joined by strong, symmetric (Ci) hydrogen bond with the O⋯O distance of 2.473 Å at room temperature. Powder FT-IR and FT-Raman as well as solid state 13C NMR spectra provide insights into the solid structure of this complex, character of its hydrogen bonds and the β-alanine protonation.

Adres publiczny

https://doi.org/10.1016/S1386-1425(02)00116-6

Strona internetowa wydawcy

http://www.elsevier.com

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