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Inne
Histaminol and its complexes with copper(II) : studies in solid state and solution.
Autorzy
Rok wydania
2018
Czasopismo
European Journal of Inorganic Chemistry
Strony
1399-1408
DOI
10.1002/ejic.201701411
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Histaminol [4(5)‐(β‐hydroxyethyl)imidazole, 4‐(1H‐imidazol‐2‐yl)ethanol, L] is an analogue of histamine and its minor metabolite. So far its properties have not been studied in detail due to the synthetic difficulties. Here, the structure and acid‐base properties of histaminol, as well as the results of studies on its copper(II) complexes in solid state and aqueous solution are reported. Stability constants of the histaminol–CuII system are measured and each stage of the complex formation is illustrated with the relevant crystal structure and the EPR spectrum.
Słowa kluczowe
copper, histaminol, x-ray diffraction, EPR spectroscopy, stability constants
Adres publiczny
https://doi.org/10.1002/ejic.201701411
Strona internetowa wydawcy
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