Wydział Chemii

Mirosław Karbowiak

Janusz Drożdżyński

1990

Journal of the Less-Common Metals

163

159-164

10.1016/0022-5088(90)90095-2

Naukowa

Angielski

Artykuł

A new U(III) compound of the formula CsUCl₄·4H₂O has been synthesized, and some of its structural, spectroscopic and magnetic properties have been determined. The complex chloride belongs to the monoclinic system with , , , β = 99.28° and Z = 2. Magnetic susceptibility measurements were carried out by the Faraday method in the 4.2–300 K temperature range. The Curie-Weiss law is followed in the 180–300 K region with the paramagnetic constants μ_eff = 3.27 B.M. and θ = 29 K. The IR and electronic spectra of the compound in the solid state were recorded in the 80–4000 cm⁻¹ and 4000–25 000 cm⁻¹ absorption ranges respectively and are discussed.

https://doi.org/10.1016/0022-5088(90)90095-2

http://www.elsevier.com