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Why does the 2,2'-bipyridine-4-methyl-3,3'-dicarboxylic acid not form MOFs: synthesis, crystal structure and properties of a new organic ligand.
Autorzy
Rok wydania
2015
Czasopismo
Journal of Chemical Crystallography
Numer woluminu
45
Strony
363-368
DOI
10.1007/s10870-015-0591-1
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
2,2′-Bipyridine-4-methyl-3,3′-dicarboxylic acid monohydrate (1) is introduced as a new organic ligand. Synthesis, structure and properties (TGA, IR, NMR) are characterized. 1 includes an extensive hydrogen bonding network with formation of various graph-set motifs, such as R 2 2 (18) R22(18) or R 10 12 (40) R1210(40) . In contrast to the related compounds, 1 does not participate in formation of MOFs. This is rationalized based on DFT calculations showing that the most plausible conformations of 1 do not favour coordination of a metal ion.
Słowa kluczowe
single crystal structure analysis, organic ligands, x-ray diffraction, hydrogen bonding
Adres publiczny
http://dx.doi.org/10.1007/s10870-015-0591-1
Strona internetowa wydawcy
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