Repozytorium

Synthesis and structural studies of novel Cu(II) complexes with hydroxy derivatives of benzo[b]furan and coumarin.

Autorzy

Aleksandra Drzewiecka

Anna E. Kozioł

Marcin T. Klepka

Anna Wolska

H. Przybylinska

Sonia B. Jimenez-Pulido

Kinga Ostrowska

Marta Struga

J. Kossakowski

Tadeusz Lis

Rok wydania

2012

Czasopismo

Polyhedron

Numer woluminu

43

Strony

71-80

DOI

10.1016/j.poly.2012.05.042

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

A series of new Cu(II) complexes with the hydroxy derivatives of benzo[b]furan and coumarin have been electrochemically synthesized. The geometry of the metal–ligand interaction has been described using the single crystal X-ray diffraction method and X-ray absorption spectroscopy. Two ligands are bonded to the metal cation via the acetyl and deprotonated hydroxyl O atoms. The centrosymmetric coordination polyhedron of Cu(II) exhibits a square-planar geometry (CuO4), with both ligands coordinating in the chelating mode.

Słowa kluczowe

Cu(II) complex, Benzo(b)furan derivatives, Coumarin derivatives, crystal structure, XAS study

Adres publiczny

https://doi.org/10.1016/j.poly.2012.05.042

Strona internetowa wydawcy

http://www.elsevier.com

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