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Inne
Reorientational and vibrational relaxation in liquid trichloracetonitrile.
Autorzy
Rok wydania
1986
Czasopismo
Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy
Numer woluminu
42
Strony
799-805
DOI
10.1016/0584-8539(86)80107-6
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The first- and second-order reorientational correlation functions were determined from i.r. and Raman bandshapes of νs(CN)in liquid trichloracetonitrile and discussed in terms of the J-diffusion model. A consistent fit for G1r(t) and G2r(t) was possible for short times only (0–1.5 ps). The vibrational correlation functions, determined from Raman studies of the νs(CN) and νs(CC) bandshapes, are discussed in terms of recent theories of vibrational dephasing.
Adres publiczny
https://doi.org/10.1016/0584-8539(86)80107-6
Strona internetowa wydawcy
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