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Inne
Water chain and water tapes in the crystals of brucinium chlorate(VII) dihydrate and brucinium dihydrogen phosphate (V) 6.15 hydrate.
Autorzy
Rok wydania
2006
Czasopismo
Journal of Molecular Structure
Numer woluminu
791
Strony
144-148
DOI
10.1016/j.molstruc.2006.01.022
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The crystal structures of brucinium chlorate(VII) dihydrate and brucinium dihydrogen phosphate 6.15 hydrate were determined. In both crystals, brucinium cations form common monolayer sheets, and anions and water molecules are found between them. In the crystal of 1, the only water molecules, which form helical chain C4, participate in short hydrogen bonds with cations and anions. Both, cation and anion are linked only by weak C–H⋯O hydrogen bonds. In the crystal of 2, brucinium-dihydrogen phosphate(V) ions pair is directly linked by short ionic N–H+⋯O− hydrogen bond, and water molecules form common tapes T6(2) or T5(2).
Słowa kluczowe
Water clusters, Chirality, X-ray diffraction studies, Brucinium salts
Adres publiczny
https://doi.org/10.1016/j.molstruc.2006.01.022
Strona internetowa wydawcy
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