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Reduction of rhenates (VII) with hydrogen chloride in alcohols: the structural aspects of the trans -tetrachloridomethoxidooxidorhenate(VI) products.

Autorzy

Małgorzata Hołyńska

Stefane Dehnen

Florian Weigend

Tadeusz Lis

Rok wydania

2014

Czasopismo

Inorganica Chimica Acta

Numer woluminu

411

Strony

26-29

DOI

10.1016/j.ica.2013.11.010

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

A series of phosphonium trans-tetrachloridomethoxidooxidorhenates(VI) was isolated as primary products of the reaction of rhenate(VII) anions with hydrogen chloride in alcohols. The complex [ReOCl4(OCH3)]− anion structure is investigated in detail. It is shown, that in the [ReOCl4(OCH3)]− anion no trans influence of the formally “triple” Re–O bond is present as a result of the “ligands competition effect”. Additionally, quantum-chemical investigations were performed to elucidate the steric and electronic influence of different alkoxido substituents.

Słowa kluczowe

Rhenium (VI), trans influence, X-ray diffraction studies, DFT studies

Adres publiczny

http://dx.doi.org/10.1016/j.ica.2013.11.010

Strona internetowa wydawcy

http://www.elsevier.com

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