Repozytorium
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Kolekcje
Inne
Magnetic properties, crystal and molecular structure of (Nbu4)2[ReCl4(ox)].
Autorzy
Rok wydania
2001
Czasopismo
Journal of Molecular Structure
Numer woluminu
595
Strony
225-231
DOI
10.1016/S0022-2860(01)00551-8
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The synthesis, structure and magnetic properties of the rhenium(IV) complex (NBu4)2[ReCl4(ox)] is reported. The crystal and molecular structure (NBu4)2[ReCl4(ox)] has been solved by the heavy atom method and refined anisotropically to unique observed reflections. The title compound crystallizes in the monoclinic space group P21/n with Z=4. The Re atom is of six-coordinate distorted octahedral configuration being bonded to one bidentate oxalate group and four chloride anions. The asymmetric unit contains one [ReCl4(ox)]− 2 anion and two [NBu4]+ cations. The magnetic behavior of (NBu4)2[ReCl4(ox)] has been investigated over the temperature range 1.72–300 K. This measurement revealed that examined compound is magnetically diluted with the great value of zero-field splitting parameter
Słowa kluczowe
Rhenium(IV) complexes, Magnetism, Oxalate group, Crystal structure, IR spectra
Adres publiczny
https://doi.org/10.1016/S0022-2860(01)00551-8
Strona internetowa wydawcy
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