Repozytorium
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Kolekcje
Inne
Crystal structure and magnetic properties of hexachlororhenates(IV) with aromatic amine cations.
Autorzy
Rok wydania
2002
Czasopismo
Journal of Molecular Structure
Numer woluminu
641
Strony
109-117
DOI
10.1016/S0022-2860(02)00010-8
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Complexes of the form (AH)2ReCl6 (A=Py, Qy) are characterized using X-ray studies and magnetic measurements over the 1.72–300 K temperature range. The pyridine and quinoline salts crystallize in the triclinic system and the space group P1̄. All compounds indicating the presence of antiferromagnetic interactions and the magnetic susceptibility curves exhibits the maximum at 4.25 K for (PyH)2ReCl6 and at 3.57 K for (QyH)2ReCl6·2H2O. Their octahedral ReCl62− anions are packed with planar amine cations so that the octahedra form alternating layers with the organic moieties, and the usual bond lengths and angles are maintained.
Słowa kluczowe
Rhenium(IV), Magnetism, X-ray study, Hydrogen bonds
Adres publiczny
https://doi.org/10.1016/S0022-2860(02)00010-8
Strona internetowa wydawcy
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