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Inne
Phenylacetylene semihydrogenation over a palladium pyrazolate hydrogen-bonded network.
Autorzy
Rok wydania
2021
Czasopismo
Numer woluminu
518
Strony
120255/1-120255/7
DOI
10.1016/j.ica.2021.120255
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The palladium azolate/carboxylate network (Pd-dmpzc) catalyses the selective hydrogenation of phenylacetylene to styrene in water. Under optimised conditions, at a Pd:NaBH4 ratio of 1:100 at 40 °C, Pd-dmpzc provided much better results than Pd(OAc)2 or PdCl2(CH3CN)2. Analysis of the recovered catalyst revealed the presence of different Pd2+ species and Pd0 NPs which contributed in the catalytic reaction.
Słowa kluczowe
palladium, Semihydrogenation, Phenylacetylene, hydrogen-bonded network, hydrogen transfer
Adres publiczny
http://dx.doi.org/10.1016/j.ica.2021.120255
Strona internetowa wydawcy
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