Wydział Chemii

Andrzej Burakowski

Jacek Gliński

Bogusława Czarnik-Matusewicz

Paulina Kwoka

Andrzej Baranowski

Kazimierz Jerie

Helge Pfeiffer

Nikos Chatziathanasiou

2012

Journal of Physical Chemistry B

116

705-710

10.1021/jp210664g

Naukowa

Angielski

Artykuł

Aqueous solutions of 2,2,2-trifluoroethanol appear to show a structural transition at alcohol mole fraction equal to x(TFE) = 0.05, which can be concluded from a discontinuity of the speed of sound. At the same concentration, a discontinuity was observed in the parameters of the long-living component of the positron annihilation spectrum. Moreover, the partial molar volumes of components show transition-like behavior in the range of low solute contents, which is significantly different from nonsubstituted ethanol. The peculiarities of the low concentration system correlate with minor infrared spectra changes assigned to a mode composed of the CH(2) bending and CF(3) stretching internal vibrations being sensitive to polarity of the hydration shell surrounding the solute. The majority of the spectral changes arise from a gradual shift of the equilibrium between trans ↔ gauche isomers when the composition of the solution is changing. A possible explanation for the peculiar behavior of the system is a thermodynamic equilibrium between hydrated monomers and dimers at that respective mole number.

http://dx.doi.org/10.1021/jp210664g

https://www.acs.org/content/acs/en.html