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Compressibility of aqueous solutions of nonelectrolytes:an equilibrium model.
Autorzy
Rok wydania
2010
Czasopismo
Numer woluminu
132
Strony
124507/1-124507/5
DOI
10.1063/1.3356052
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
In this paper the parabolic-shaped dependences of compressibility κS of a nonelectrolyte in water solvent on concentration are explained and described semiquantitatively in terms of hydrate formation equilibrium reaction. It was demonstrated that only two fitted parameters, the hydration number nh and the formation constant of the hydrate K, are sufficient to reproduce satisfactorily the experimental data, in particular the characteristic minimums of κS versus composition observed at low contents of solutes.
Adres publiczny
https://doi.org/10.1063/1.3356052
Strona internetowa wydawcy
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