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Kolekcje
Inne
Synthesis, structure and magnetic characterization of the first azido bridged heterotetranuclear chromium-sodium complex.
Autorzy
Rok wydania
2013
Czasopismo
Inorganic Chemistry Communications
Numer woluminu
35
Strony
172-175
DOI
10.1016/j.inoche.2013.06.009
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The first mixed-metal azido bridged complex of Cr(III)–Na(I) has been prepared and its structure is determined. Reaction of chromium(III) chloride and sodium azide with bis-[(E)-N′-(1-(pyridin-2-yl)ethylidene)]carbohydrazide (HL) produced the tetranuclear complex [Cr2Na2(L)2(CH3OH)2(μ-N3)4(N3)2] (1) in good yield. The structure is composed of idealized octahedral [CrIII(N5O)] cores linked to the octahedral [Na(N4O2)] cores by two bridging azide ligands. Magnetic properties and EPR of 1 were also studied.
Słowa kluczowe
heterotetranuclear, carbohydrazide, azide, structure, Magnetic properties
Adres publiczny
http://dx.doi.org/10.1016/j.inoche.2013.06.009
Strona internetowa wydawcy
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