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Inne
"Push-pull" 2-ferrocenyl-4-hydroxythiazoles: a novel method of the construction of the thiazole ring.
Autorzy
Rok wydania
2008
Czasopismo
Journal of Organometallic Chemistry
Numer woluminu
693
Strony
2982-2986
DOI
10.1016/j.jorganchem.2008.04.043
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The title compounds were obtained by cyclization of ferrocenyl thioimidates in the presence of sodium ethoxide. They were transformed into the corresponding 4-acetoxy-derivatives in reaction with acetic anhydride/pyridine. The structure of 4-acetoxy-5-(ethoxycarbonyl)-2-ferrocenylthiazole was determined by X-ray diffraction. The EFISH measurements revealed significant second-order nonlinear properties of 4-acetoxy-2-ferrocenyl-5-(4-nitrophenyl)ferrocenylthiazole (μβ = 250 × 10−48 esu at 1907 nm).
Słowa kluczowe
Ferrocene, Thiazole, Cyclization, X-ray structure, NLO, EFISH
Adres publiczny
https://doi.org/10.1016/j.jorganchem.2008.04.043
Strona internetowa wydawcy
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