Repozytorium
Wyszukaj
Kolekcje
Inne
Phenanthrene‐Embedded Carbaporphyrinoids and Related Systems: From Ligands to Cages and Molecular Switches
Autorzy
Rok wydania
2022
Czasopismo
European Journal of Organic Chemistry
Strony
e202200714/1-e202200714/16
DOI
10.1002/ejoc.202200714
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
This Review discusses the recent developments in the field of synthetic chemistry of PAH–porphyrin hybrids, emphasizing phenanthrene-embedded carbaporphyrinoids and related systems. The discussion covers various aspects of phenanthriporphyrin and its derivates chemistry, including their spectroscopic features, aromaticity, core reactivity, and coordination properties. The development of expanded phenanthriporphyrinoids is outlined, followed by the presentation of related carbaporphyrinoids incorporating hydrocarbon moieties such as fluorene, biphenyl, terphenyl, and dibenzo[g,p]chrysene. The exploitation of phenanthriporphyrinoids as a unique class of ligands for organometallic chemistry is discussed, altogether with their use for the construction of conformational and stereochemical switches. The perspective for using related macrocycles as building blocks for carbaporphyrinoid cages is also outlined.
Słowa kluczowe
Aromaticity, Chirality, Macrocycles, Porphyrinoids, Supramolecular chemistry
Adres publiczny
http://dx.doi.org/10.1002/ejoc.202200714
Strona internetowa wydawcy
Podobne publikacje
Kinetic versus thermodynamic control over multiple conformations of di‐2,7‐naphthihexaphyrin(1.1.1.1.1.1)
Szyszko Bartosz, Rymut Paweł, Matviyishyn Maksym, Białońska Agata, Latos-Grażyński Lechosław
N-fusion approach in construction of contracted carbaporphyrinoids: formation of N-fused telluraporphyrin.
Pacholska-Dudziak Ewa, Ulatowski Filip, Ciunik Zbigniew, Latos-Grażyński Lechosław
Janus Reactivity of Crownphyrinoids: Alkali‐ vs. Transition Metal‐Mediated Transformations of Crown Ether‐Porphyrin Hybrids
Matviyishyn Maksym, Konieczny Krzysztof A., Trzaskowski Bartosz, Szyszko Bartosz