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N-fusion approach in construction of contracted carbaporphyrinoids: formation of N-fused telluraporphyrin.
Autorzy
Rok wydania
2009
Czasopismo
Numer woluminu
15
Strony
10924-10929
DOI
10.1002/chem.200900841
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Insertion of PCl3 into 5,10,15,20-tetraaryl-21-telluraporphyrin leads to a phosphorus complex of N-fused dihydrotelluraporphyrin with an inverted tellurophene ring. Its CNN coordination core places the macrocycle in the family of contracted carbaporphyrinoids. A cycle of direct transformations affords an elegant triangle of three mutually convertible N-fused porphyrinoids, with distinct spectroscopic features: antiaromatic, nonaromatic and aromatic. The nonaromatic species has a dome shaped skeleton which forms in the solid state a ball and socket structure with C60.
Słowa kluczowe
fullerenes, macrocycles, porphyrinoids, template synthesis, supramolecular chemistry
Adres publiczny
http://dx.doi.org/10.1002/chem.200900841
Strona internetowa wydawcy
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