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Inne
Crystal structure of pyridynium pentachloro(pyridine)rhenate(IV), (C5H6N)(C5H5N)ReCl5.
Autorzy
Rok wydania
2003
Czasopismo
Zeitschrift für Kristallographie - New Crystal Structures
Numer woluminu
218
Strony
207-208
DOI
10.1524/ncrs.2003.218.2.207
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Transition metal complexes with aromatic amines ligands have been discussed in recent reviews [2-4]. Rhenium(IV) complexes
with aromatic amine in the coordination sphere indicate antiferromagentic interactions [5].The title compound has slightly distorted octahedral environment around the Re atom. The bonds lengths are d(Re—N) = 2.17(1) Å, d(Re—Cl1) = 2.352(3) Å, d(Re—Cl2) = 2.355(3) Å and d(Re—Cl3) = 2.357(4) Å. The plane of pyridine ring intersects the plane formed by the Re and four chlorine atoms. In the 010 direction the orientation of the molecules shows a pseudo layered
structure. The ReCl5 1– moieties alternate with pyridine situated in the layers.
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