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Inne
Rare monomeric-dimeric copper(II) cinnamate complexes in one single crystal : syntheses, characterization, structure determination and DFT studies of two copper(II) complexes.
Autorzy
Rok wydania
2012
Czasopismo
Inorganic Chemistry Communications
Numer woluminu
20
Strony
209-213
DOI
10.1016/j.inoche.2012.03.010
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Rare monomeric as well as dimeric Cu(II) complexes, [Cu2(β-pic)4L4][Cu(β-pic)2L2(H2O)2]·2H2O (1), (where L = cinnamate and β-pic = β-picoline) in one single crystal have been synthesized by the reaction of copper(II) cinnamate and excess of β-pic while a monomeric complex [Cu(py)2L2(H2O)]·py (2) was obtained in a similar reaction by using py (py = pyridine) instead of β-pic. Both of these copper(II) complexes have been characterized by spectroscopic techniques, TGA, X-ray crystallography and DFT studies.
Słowa kluczowe
copper(II) complex, Monomer–dimer, X-ray crystallography, DFT studies, EPR
Adres publiczny
https://doi.org/10.1016/j.inoche.2012.03.010
Strona internetowa wydawcy
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