Wydział Chemii

Ludmila I. Kveglis

Fedor M. Noskov

Mikhail N. Volochaev

Alexander V. Nyavro

Aleksander Filarowski

2021

Symmetry

13

665/1-665/13

10.3390/sym13040665

Naukowa

Angielski

Artykuł

This paper focuses on the processes of the occurrence of magnetization during structure formation in samples of Ni₅₁Ti₄₉ alloy under deformation conditions. The possibility of the existence of a phase with an FCC (face-centered cubic) lattice in titanium nickelide has been demonstrated by electron microscopy and electron diffraction. It has been discovered that the interplanar distances of BCC₁₁₀ (body-centered cubic), FCC₁₁₁, and HCP₀₀₂ (hexagonal close packed) in the alloy under study have similar values, which indicates the possibility of their mutual polymorphic transformation. Based on the modular self-organization, a scheme of martensitic transformations in titanium nickelide from the B2 structure (BCC lattice) to the B19’ structure (HCP lattice) through an intermediate phase with an FCC lattice is proposed. It is shown that lenticular crystals appear in the Ni₅₁Ti₄₉ alloy under tensile deformation until rupture, which is accompanied by the onset of ferromagnetism. The effect of magnetization in Ni₅₁Ti₄₉ samples when immersed in liquid nitrogen has been also discovered. In this case, the reason for the appearance and disappearance of magnetization can be associated with microdeformation processes caused by direct and reverse martensitic transitions that occur during cooling and heating of the samples.

titanium nickelide, deformation, martensitic transformation, electron diffraction, ferromagnetism, clusters

CC-BY

http://dx.doi.org/10.3390/sym13040665

http://www.mdpi.com/journal/metals