Repozytorium

Crystal structure and magnetic characteristics of a new 3-methylisoquinolinium tetrachloridoferrate(III).

Autorzy

Dariusz Wyrzykowski

Artur Sikorski

Julia Kłak

Jerzy Mroziński

E. Styczeń

Zygmunt Warnke

Rok wydania

2009

Czasopismo

Zeitschrift für Anorganische und Allgemeine Chemie

Numer woluminu

635

Strony

1249-1253

DOI

10.1002/zaac.200801257

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The crystal structure of a new 3-methylisoquinolinium[3-Me(IsoQH)] salt, [3-Me(IsoQH)][FeCl4], was determined. The iron cation is tetracoordinated by chlorine anions, and it adopts a slightly distorted tetrahedral coordination. In the crystal structure, there are π···π stacking interactions between the 3-methylisoquinolinium cations in an ABAB infinite arrangement, N–H···Cl hydrogen bonds, and C–H···Cl intermolecular interactions. Magnetic measurements of a powdered sample were carried out. A negative Weiss constant as well as the intermolecular exchange parameter for [3-Me(IsoQH)][FeCl4] indicate the occurrence of antiferromagnetic interactions transmitted in the crystal lattice.

Adres publiczny

https://doi.org/10.1002/zaac.200801257

Strona internetowa wydawcy

onlinelibrary.wiley.com

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