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Cyclic water pentamers in triclinic crystals of brucinium L-glycerate.
Autorzy
Rok wydania
2005
Czasopismo
Acta Crystallographica Section C: Structural Chemistry
Numer woluminu
C61
Strony
88-91
DOI
10.1107/S0108270104031853
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Brucinium L-glycerate 4.75-hydrate, C23H27N2O4+.C3H5O4-.4.75H2O, was obtained by racemic resolution of DL-glyceric acid. This is the first report of triclinic crystals containing brucine. The water and L-glycerate anions form tapes built up of pentamers formed by water and carboxy O atoms, and this appears to be the reason for the low symmetry of the crystal.
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2006