Repozytorium

Tetradecanuclearity in 3d—4f chemistry : relaxation and magnetocaloric effects in [NiII6LnIII8] species.

Autorzy

Angelos B. Canaj

Dimitris A. Kalofolias

Miłosz Siczek

Tadeusz Lis

Robbie McNab

Giulia Lorusso

Ross Inglis

Marco Evangelisti

Constantinos J. Milios

Rok wydania

2017

Czasopismo

Dalton Transactions

Numer woluminu

46

Strony

3449-3452

DOI

10.1039/c7dt00102a

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The employment of 2-amino-isobutyric acid, Haib, and 2-hydroxy-1-naphthaldehyde, Hnaphth, in NiII/LnIII chemistry has led to the isolation and characterization of two new isostructural 3d–4f tetradecanuclear [NiII6LnIII8] clusters (Ln = GdIII, DyIII), with the Dy analogue displaying temperature and frequency dependent out-of-phase signals, and the Gd analogue showing interesting magnetocaloric properties.

Adres publiczny

http://dx.doi.org/10.1039/c7dt00102a

Strona internetowa wydawcy

https://www.rsc.org/

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